![]() FIBER APPLICATION HEAD WITH FLEXIBLE ROLL WITH METALLIC OUTER LAYER
专利摘要:
The present invention relates in particular to a fiber application head for producing composite material parts, comprising a compacting roll (2) for applying a strip formed of one or more flat fibers to a surface (S). ) of application, a heating system (9) capable of emitting thermal radiation in the direction of the strip, just before application by the application roller, said compaction roller comprising a central tube (5) rigid and at least one cylinder (3) made of a flexible material, elastically deformable, assembled on said central tube, characterized in that said compaction roller further comprises an outer layer (6) metal. 公开号:FR3044255A1 申请号:FR1502490 申请日:2015-11-27 公开日:2017-06-02 发明作者:Johann Caffiau;Jean Philippe Weber 申请人:Coriolis Composites SAS; IPC主号:
专利说明:
The present invention relates to a fiber application head for a fiber application machine for producing parts made of composite material, and more particularly to a so-called fiber placement head equipped with a particular application roller. The present invention also relates to a method of manufacturing parts made of composite material by means of a corresponding application head. Fiber application machines, commonly known as fiber placement machines, are known for contacting drape tools, such as a male or female mold, with a wide web of multiple flat fibers. continuous, ribbon type, dry or impregnated with thermosetting or thermoplastic resin, especially carbon fibers consisting of a multitude of carbon threads or filaments. These machines are used to produce preforms formed of several superimposed folds, each fold being formed by draping on the mold of one or more strips side by side. In the case of a lay-up of fibers pre-impregnated with thermoplastic or thermosetting resin, conventionally in an amount of at least 40% by weight, the prepreg preform obtained after draping is cured or polymerized by passing through an oven to obtain a piece of composite material. In the case of so-called dry fibers, which are not pre-impregnated with resins, the fibers comprise a reduced quantity of so-called binding resin, also called a binder, generally a thermoplastic resin, in an amount of less than or equal to 5% by weight, to give a character sticky to the fibers during draping. After draping, the so-called dry preform is subjected to an injection or resin infusion operation before the hardening step. These machines, as described in patent document WO2006 / 092514, conventionally comprise a fiber application head, a displacement system of said head, fiber storage means, and fiber delivery means for conveying the fibers. fibers of said storage means to the head. The head conventionally comprises an application roller, also called compaction roller, intended to come into contact against the mold for applying the strip, and fiber guiding means on said application roller. The head further generally comprises a heating system for heating the fibers. The compaction roller presses the fiber web against the application surface of the mold, or against the previously deposited fiber web or strips, in order to facilitate the adhesion of the strips deposited between them, as well as to progressively evacuate trapped air between the deposited tapes. The heating system provides a heating of the fiber web to be applied, and / or the mold or strips already applied upstream of the compaction roller, just before the compaction of the web, in order to at least soften the resin of pre impregnation or binding resin, and thus promote the adhesion of the strips together. In the case of thermosetting resins, the prepreg fibers are simply heated to soften them, typically at temperatures of the order of 40 ° C. The heating system conventionally comprises an infrared heating system comprising one or more infrared lamps. In the case of thermoplastic resins, the preimpregnated or bindered fibers must be heated to higher temperatures, at least up to the melting temperature of the resin, of the order of 200 ° C for resins nylon type, and up to about 400 ° C for PEEK type resins. To achieve these higher temperatures, it has been proposed hot air torch systems, and more recently laser type heating systems to achieve precise and concentrated heating. Due to the high heating temperatures, the fiber placement heads are conventionally equipped with heat-resistant metal compacting rollers, which can further be cooled from the inside via a water circuit. To be able to adapt to the profile of the application surface, it has been proposed segmented metal compacting rollers, comprising several independent roller segments mounted side by side on the same axis, each segment being movable radially and independently, and being resiliently biased against the application surface. These segmented metal rollers, however, are complex in structure and implementation. Flexible rolls formed from a so-called high temperature elastomer, including a thermal stabilizer, are also used. To cool them, it has been proposed to equip the placement heads with a cooling system capable of delivering a flow of air to cool the roll from the outside or from the inside, as described in the patent document FR 2948058. Despite these cooling systems, the flexible rolls may tend to deteriorate rapidly in the case of the implementation of thermoplastic resins. The object of the present invention is to provide a solution to overcome the aforementioned drawbacks, which allows in particular the implementation of a wide variety of resins, both thermosetting and thermoplastic, with a substantially uniform compacting of the applied band, and which be simple of design and realization. For this purpose, the present invention proposes a fiber application head for the production of composite material parts, comprising a compaction roll, also called application roll, for the application of a strip formed of a or a plurality of flat fibers on an application surface, and preferably a guiding system for guiding at least one fiber to said application roller, a heating system capable of emitting heat radiation in the direction of the web just prior to application by the application roller, said compacting roller comprising a rigid central tube by which said roller is rotatably mounted on a support structure of the head, and at least one cylinder made of a flexible or flexible material, elastically deformable, assembled coaxially, directly or indirectly on said central tube, characterized in that said compacting roller further comprises an outer layer e metal. According to the invention, the roll is equipped with a flexible, thin metal outer layer, for example formed of a sheet or metal strip, by which said roll is intended to come into contact with the application surface. Said metal layer serves as a screen for thermal radiation emitted by the heating system, and avoids overheating of the compaction roller. Said metal layer is flexible, so that the roll can be deformed to allow draping with a compacting force. After compacting, the cylinder of flexible material resumes its original shape and urges the metal layer to its cylindrical shape. The cylinder of flexible material thus protected from thermal radiation, does not rise in temperature and degrades little. Moreover, the thin metal layer, stores little heat, and it dissipates quickly. The use of a metal layer according to the invention makes it possible to obtain a thermally stable flexible compaction roller that can be used for applying fibers at high temperatures, in particular greater than 400.degree. C., in particular for applying fibers. impregnated with thermoplastic resins. The head according to the invention, which comprises a compact compaction roller simple design, offers the possibility of using a wide variety of thermosetting or thermoplastic resins combined with a wide variety of fibers, synthetic or natural, hybrid or not, including fibers commonly used in the field of composites, such as glass fibers, carbon fibers, quartz fibers, and aramid fibers. According to one embodiment, said metal layer is formed of a strip or metal foil, preferably in the form of a so-called seamless belt, preferably having a thickness of between 20 micrometers (0.02 millimeters) and 200 micrometers (0.2 millimeters), preferably between 50 micrometers (0.05 millimeters) and 150 micrometers (0.15 millimeters), for example of the order of 100 micrometers (0.1 millimeter). Such a strip returns elastically in its original cylindrical shape under the effect of the cylinder of flexible material. Surprisingly, it has been found that the roller according to the invention can not only be used for draping on substantially flat surfaces, with a so-called two-dimensional deformation of the metal layer, but also on surfaces of complex geometries, with a so-called three-dimensional deformation of the metal layer. According to one embodiment, said metal layer is formed of a steel strip, preferably stainless steel. According to other embodiments, said strip is made of brass, copper, or bronze. According to one embodiment, said metal strip has on its outer face a non-stick treatment and / or a reflective treatment, said strip being for example provided with a release and / or reflective film. According to one embodiment, said metal layer is bonded to said cylinder. According to other embodiments, said metal layer is formed by deposition of thin layer on the cylinder, for example by vacuum plasma deposition, in particular a thin layer of gold. According to one embodiment, said compaction roller comprises a cylinder of an elastomer material, preferably unexpanded, for example a silicone or a polyurethane, preferably silicone, preferably having a hardness of between 25 Shore A and 80 Shore A . According to one embodiment, the compaction roll comprises a foam cylinder, for example an expanded elastomer such as a polyurethane foam, preferably having a density of between 200 kg / m 3 and 500 kg / m 3. According to one embodiment, said compacting roller comprises a first foam cylinder assembled on the central tube and a second cylinder of elastomeric material assembled on the first cylinder, said metal layer being assembled on the second cylinder. According to one embodiment, the head comprises a cooling system capable of cooling the application roller from outside and / or inside, preferably at least from the outside, the head possibly comprising a drive system. adapted to rotate the application roller, when the roller is not in contact with the application surface. According to one embodiment, said roll is externally cooled by a gaseous flow directed towards its cylindrical outer surface during the application operations, during the laying paths and the connecting paths, and as well as preferably when the head is in the waiting position. According to one embodiment, the compaction roll comprises at least one temperature sensor mounted on the internal face of the metal layer, in particular the internal face of a strip, preferably several temperature sensors distributed at regular angular space and / or or at regular intervals along the length of the roll, the sensors, in particular of the thermocouple type, being preferably assembled on said internal face. According to one embodiment, the head constitutes a fiber placement head comprising cutting means and means of rerouting, and possibly fiber blocking means. According to one embodiment the head is used to perform a filament winding type application. According to one embodiment, said heating system is a laser-type system, in particular laser diodes, a YAG laser or a fiber laser. Alternatively, the heating system may include one or more infrared lamps. The present invention also relates to a method of manufacturing a composite material part comprising the application of continuous fibers to an application surface, characterized in that the application of fibers is carried out by means of a head of application of fibers as defined above, by relative displacement of the application head relative to the drape surface according to removal paths, the fibers being compacted during their application by means of said application roll. The fibers conventionally used are continuous flat fibers, also called wicks, generally unidirectional, and comprising a multitude of filaments. The deposited fibers may be dry fibers or fibers pre-impregnated with thermosetting or thermoplastic resin. The fibers typically have widths of 1/8, 1/4 or 1/2 inches. As used herein, the term "fibers" also refers to fibers of greater width, greater than 1/2 inch, conventionally referred to as a strip in placement technology. The method according to the invention is particularly advantageous in the case of the production of dry preforms made from dry fibers provided with a binder and / or thermoplastic preforms made from fibers pre-impregnated with thermoplastic resin, requiring temperatures. high heating during draping to at least reach the melting point of the binder and / or thermoplastic resins. In the case of a dry preform, the method further comprises a resin impregnation step in the dry preform, by adding one or more impregnation resins by infusion or injection to the dry preform, and a step of hardening to obtain a composite material part. In the case of a thermoplastic preform, the preform may optionally be subjected to an additional consolidation step to obtain a final piece of composite material. In situ consolidation can also be achieved when fiber is applied. The application of fibers may be performed on the application surface of a tool to form a preform, as described above. According to another embodiment, the application of fibers is carried out directly on the application surface of a prefabricated part, to reinforce this part with unidirectional fiber reinforcements, the prefabricated part being for example a part obtained by injection, molding or additive manufacturing, from one or more thermoplastic and / or thermosetting resins. The invention will be better understood, and other objects, details, features and advantages will become more clearly apparent from the following detailed explanatory description of particular embodiments currently preferred of the invention, with reference to the accompanying schematic drawings, in which: - Figure 1 is a schematic side view of a fiber application head according to the invention, illustrating the compacting roller and the heating system; FIG. 2 is a schematic cross-sectional view of the compacting roller of FIG. 1; - Figures 3 and 4 are diagrammatic views respectively of side and longitudinal section of the compacting roller of Figure 1, illustrating the crushing of the roll during draping; and - Figure 5 is a schematic cross-sectional view of a compacting roller according to an alternative embodiment. Referring to Figure 1, the application head 1 comprises a compacting roller 2 which is rotatably mounted about an axis A on a support structure (not shown) of the head. The head is intended for the application of a band formed of several fibers arranged side by side. The head is mounted by said support structure at the end of a displacement system, for example a robot wrist. The head further comprises a heating system 9 also mounted on the support structure, upstream of the roll with respect to the advancing direction D of the application head when the fiber web 8 is applied to a surface The heating device is, for example, a laser-type heating system, the radiation of which is directed towards the strip, just before it is compacted, as well as towards the strip or strips already deposited. As illustrated in FIG. 1, the radiation is thus directed obliquely towards the roller to heat a section of strip disposed on the roll, before it is compacted by the latter. In the case of a fiber placement machine, the head comprises guide means which guide the fibers entering the head to the compacting roller 2 in the form of a fiber web, the fibers of the web being arranged side by side substantially joined. By moving the head by the robot, the compaction roller is brought into contact with the application surface of a mold S to apply the band. The fibers are preferably flat continuous fibers, such as wicks, pre-impregnated with a thermosetting resin or a thermoplastic resin, or dry fibers provided with a binder. The binder is in the form of powder and / or one or more webs, preferably thermoplastic type. Referring to Figure 2, the compacting roller according to the invention comprises a cylindrical body or cylinder 3 of a flexible material, elastically deformable by compression. The cylinder has a central cylindrical passage for its assembly on a support core formed of a rigid cylindrical central tube, for example metallic, such as aluminum. The cylinder 3 and the central tube 5 are coaxial and are integral in rotation with each other. The cylinder is for example made of an unexpanded elastomer, such as a silicone or polysiloxane, or a polyurethane, preferably a silicone, for example a bicomponent silicone polymerizable at room temperature. The cylinder has a hardness of between 30 shore A and 70 shore A, for example 40, 50 or 60 shore, which will be chosen according to the desired crushing rate of the roller for a given compacting force, this crushing rate being defined in particular according to the complexity of the application surface. According to the invention, the cylinder 3 is externally coated with a metal outer layer 6, formed of a strip, also called sheet or foil, of thin stainless steel. The cylinder 3 of flexible material gives the compaction roller a crushing capacity ensuring efficient compaction of the fibers during draping. The rigid tube 5 allows the rotary mounting of the roll on the support structure. The compacting roller is for example mounted on the support structure of the head by the open ends of its central tube, by means of bearings. The strip 6 forms a radiation shield emitted by the heating system so that the cylinder of flexible material is not reached by said radiation. The radiation is mainly absorbed by the metal strip. A treatment is optionally applied to the outer face of the strip to give it reflective properties so that a portion of the radiation is reflected. The draping of the fibers is carried out with a compacting force. Under this compacting force, the cylinder 3 and the strip 6 deform as shown in Figure 3. When the compaction force ceases, the cylinder and the strip elastically recover their cylindrical shape. The strip assembled to the cylinder deforms with the cylinder under the effect of the compacting force, and resumes its cylindrical shape when the cylinder elastically returns to its cylindrical shape. As illustrated in Figure 4, the barrel with its strip allows the compaction roll to accommodate variations in the curvature of the application surface in the length of the roll, and thus to apply a substantially uniform pressure. on the entire tape deposited. The small thickness of the strip, combined with the elasticity of the cylinder, allows a uniform deformation, known as two-dimensional, of the strip over the entire length of the roller, parallel to the axis A, as shown in Figure 3, and a so-called three-dimensional deformation of the strip not parallel to the axis A, as shown in FIG. 4, in the elastic limit of the strip. The elastomer forming the cylinder optionally comprises charges, for example metallic, for better heat dissipation. The strip is optionally provided on its outer face with a non-stick film, in order to limit the adhesion of the roller to the fibers, as well as the fouling of the roll. For example, the strip has a thickness of about 0.1 millimeters. The strip is in the form of a metal belt, said seamless. Alternatively, the strip is formed of a rectangular piece assembled for example by gluing on the cylinder, with an end assembly overlap or edge to edge. The cylinder is formed from a silicone, said high temperature, and has a hardness of about 40 shore A. According to one embodiment, the roll is manufactured in the following manner. The tube is placed in the center of the cylindrical cavity of a mold, and the strip is placed against the cylindrical wall of the cavity, the inner face of the strip having been previously coated with an adhesion primer, or primer , for silicone. Then a silicone resin and an associated catalyst are poured into the mold. The laser-type heating system may comprise laser diodes, arranged in one or more rows, emitting radiation of wavelength (s) between 880 and 1030 nm for example, an optical fiber laser or a Y AG laser, emitting at a wavelength of the order of 1060 nm. The head may be equipped with a cooling system, for example as described in the patent application FR15 / 00676, filed on April 1, 2015 by the Applicant, able to deliver a flow of air, towards the compacting roller in order to cool said compaction roller from the outside. The roll advantageously comprises temperature sensors formed of thermocouples, assembled on the inner face of the strip, for example by welding. The thermocouples are distributed on the cylindrical surface of the strip. For example, the length of the roll is provided for draping a strip of eight fibers, the roll comprises a plurality of sensors per fiber, for example three or four, the sensors of the same set are arranged at regular angular spacing from each other, and the sets are offset from each other in the length of the roller, a distance corresponding to a fiber width. These sensors measure the temperature of the strip at different points, this temperature being proportional to the heating temperature of the fibers during draping operations. The temperature information of these sensors is retrieved by the control unit of the machine to control the heating system, in order to optimize the heating parameters of the fibers during draping, and / or to control the cooling system in order to optimize roller cooling. The thermocouple wires extend radially towards the central tube, pass through openings in this central tube and exit at the end of the central tube for their connection to the control unit. According to a variant, the roll comprises a single set of sensors distributed at regular angular space, said assembly being arranged in the center of the roll. FIG. 5 illustrates an alternative embodiment in which the compaction roller 102 comprises a cylindrical rigid central tube 5, a first cylinder 104 made of a first flexible material, assembled on the central tube, a second cylinder 103 made of a second flexible material, assembled on the first cylinder, and a strip 6 assembled on the second cylinder, these various roller components being coaxial and integral in rotation with one another. The first cylinder is preferably a first material having a hardness greater than that of the second material forming the second cylinder. In this embodiment, the deformation of the roll under the compaction force comes for example mainly from the crushing of the second material. The hardnesses of the first material and the second material, as well as the thicknesses of the first cylinder and second cylinder will be defined according to the desired crush rate. For example, the first cylinder is formed of a polyurethane foam having a density of about 350 kg / m3, and the second cylinder is formed of a silicone and has a hardness of between 35 and 40 shore A. As before, the roll can be obtained by pouring the silicone into a mold in which are placed the central tube and the strip, but by first assembling said central tube a foam cylinder. The foam cylinder is for example formed by wrapping around the cylinder of the foam in the form of a plate. Although the invention has been described in connection with various particular embodiments, it is obvious that it is not limited thereto and that it comprises all the technical equivalents of the means described and their combinations if they are within the scope of the invention.
权利要求:
Claims (11) [1" id="c-fr-0001] Fiber application head for the production of composite material parts, comprising a compacting roll (2, 102) for applying a strip formed of one or more flat fibers to a surface (S) application, and - a heating system (9) able to emit thermal radiation in the direction of the strip, just before application by the application roller, said compacting roller comprising a central tube (5) rigid and at least a cylinder (3; 103, 104) made of a flexible material, elastically deformable, assembled on said central tube, characterized in that said compacting roller further comprises an outer layer (6) metal. [2" id="c-fr-0002] 2. Head according to claim 1, characterized in that said metal layer (6) is formed of a metal strip having a thickness of between 20 micrometers and 200 micrometers. [3" id="c-fr-0003] 3. Head according to claim 2, characterized in that said metal layer (6) is formed of a steel strip. [4" id="c-fr-0004] 4. Head according to claim 2 or 3, characterized in that said metal strip (6) has on its outer face a non-stick treatment and / or a reflective treatment, said strip being for example provided with a release film and / or reflective. [5" id="c-fr-0005] 5. Head according to one of claims I to 4, characterized in that said metal layer (6) is bonded to said cylinder (3, 103). [6" id="c-fr-0006] 6. Head according to one of claims 1 to 5, characterized in that said compacting roller (2, 102) comprises a cylinder (3, 103) of an elastomeric material, having a hardness of between 25 shore A and 80 shore AT. [7" id="c-fr-0007] 7. Head according to one of claims 1 to 6, characterized in that the compaction roller (102) comprises a cylinder (104) foam having a density of between 200 kg / m3 and 500 kg / m3. [8" id="c-fr-0008] 8. Head according to claims 6 and 7, characterized in that said compaction roller (102) comprises a first foam cylinder (104) assembled on the central tube (5) and a second cylinder (103) of elastomeric material assembled on the first cylinder, said metal layer (6) being assembled on the second cylinder. [9" id="c-fr-0009] 9. Head according to one of claims 1 to 8, characterized in that it comprises a cooling system capable of cooling the application roller from the outside and / or inside. [10" id="c-fr-0010] 10. Head according to one of claims 1 to 9, characterized in that the compacting roller comprises at least one temperature sensor mounted on the inner face of the metal layer. [11" id="c-fr-0011] 11. A method of manufacturing a composite material part comprising the application of continuous fibers to an application surface (S), characterized in that the application of fibers is carried out by means of an application head of fibers according to one of claims 1 to 9, by relative movement of the application head (1) relative to the drape surface (S) along the path of removal.
类似技术:
公开号 | 公开日 | 专利标题 EP2454081B1|2013-09-04|Machine for applying fibers, including a flexible compacting roller with a heat adjustment system FR2948059A1|2011-01-21|FIBER APPLICATION MACHINE WITH TRANSPARENT COMPACTION ROLL ON THE RADIATION OF THE HEATING SYSTEM EP2709831A1|2014-03-26|Fibre application head including a segmented compaction roller WO2017089659A1|2017-06-01|Fibre application head with flexible roller provided with a metallic exterior layer FR2982793B1|2019-06-28|BI-DIRECTIONAL FIBER APPLICATION HEAD WO2016146902A1|2016-09-22|Fibre application head with infrared heating system CA2862686C|2020-05-12|Method of forming a thermoplastic composite material with continuous-fibre reinforcement by stamping FR2947204A1|2010-12-31|METHOD FOR PRODUCING A FIBER PROFILE OF COMPOSITE MATERIAL HAVING A SECTION IN A HALF OF NIP OR IN A NOSE HEAD EP3277486A1|2018-02-07|Fiber application head comprising a special application roller EP3710239B1|2021-08-18|Fibre-application head having a flexible roller provided with a non-stick sleeve EP3140105A1|2017-03-15|Method and machine for creating preforms by compactionless application of oriented fibers FR2998838A1|2014-06-06|Method for manufacturing reinforcement for back of seat of automobile, involves heating set of strips by heating unit, where each of set of strips is embedded in plastic material with certain fibers extending over entire length from strips EP3140104B1|2021-06-16|Method for creating preforms by applying and shaping oriented fibers EP3426452B1|2020-02-12|Process for producing preforms with application of a binder to dry fiber, and corresponding machine EP2199069A1|2010-06-23|Production of complex composite pieces FR3100154A1|2021-03-05|FIBER APPLICATION HEAD WITH RIGID RING ROLLER WO2004067264A1|2004-08-12|Method of depositing inclined fibrous layers on a support WO2018185383A1|2018-10-11|Method for producing composite material parts from needled preforms EP3710238A1|2020-09-23|Fibre application head with air-blowing device FR3100153A1|2021-03-05|FIBER APPLICATION HEAD WITH SPECIAL SOFT ROLLER EP3711915A1|2020-09-23|Method and facility for manufacturing a rotating part made of a composite material FR3033728A1|2016-09-23|METHOD AND DEVICE FOR DRAPING AND WELDING A TEXTILE STRIP COMPRISING MICROWAVE HEATING FR3105072A1|2021-06-25|FIBER APPLICATION HEAD WITH RETRACTABLE FLAP
同族专利:
公开号 | 公开日 EP3380309A1|2018-10-03| FR3044255B1|2018-06-15| WO2017089659A1|2017-06-01|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US6390169B1|2000-02-23|2002-05-21|The Boeing Company|Conformable compaction apparatus for use with a fiber placement machine| WO2011006956A1|2009-07-17|2011-01-20|Coriolis Composites|Machine for applying fibers, including a flexible compacting roller with a heat adjustment system| FR2975334A1|2011-05-20|2012-11-23|Coriolis Composites Attn Olivier Bouroullec|FIBER APPLICATION HEAD WITH SEGMENTED COMPACTION ROLL| US20130000838A1|2011-07-01|2013-01-03|Adc Acquisition Company|Fluid medium non-contact consolidation|FR3100153A1|2019-09-02|2021-03-05|Coriolis Group|FIBER APPLICATION HEAD WITH SPECIAL SOFT ROLLER| FR3100154A1|2019-09-04|2021-03-05|Coriolis Group|FIBER APPLICATION HEAD WITH RIGID RING ROLLER|FR1500676A|1966-11-17|1967-11-03|Budd Co|Soft brake pad for disc brake| US5078821A|1990-08-13|1992-01-07|The United States Of America As Represented By The United States Department Of Energy|Method and apparatus for producing composites of materials exhibiting thermoplastic properties| FR2882681B1|2005-03-03|2009-11-20|Coriolis Composites|FIBER APPLICATION HEAD AND CORRESPONDING MACHINE|FR3073446B1|2017-11-13|2019-11-01|Coriolis Group|FIBER APPLICATION HEAD WITH SOFT ROLL WITH ANTI-ADHERENT SHEATH|
法律状态:
2016-10-20| PLFP| Fee payment|Year of fee payment: 2 | 2017-06-02| PLSC| Publication of the preliminary search report|Effective date: 20170602 | 2017-10-20| PLFP| Fee payment|Year of fee payment: 3 | 2018-10-24| PLFP| Fee payment|Year of fee payment: 4 | 2018-12-07| TP| Transmission of property|Owner name: CORIOLIS GROUP, FR Effective date: 20180925 | 2019-10-23| PLFP| Fee payment|Year of fee payment: 5 | 2020-10-21| PLFP| Fee payment|Year of fee payment: 6 | 2021-10-20| PLFP| Fee payment|Year of fee payment: 7 |
优先权:
[返回顶部]
申请号 | 申请日 | 专利标题 FR1502490A|FR3044255B1|2015-11-27|2015-11-27|FIBER APPLICATION HEAD WITH FLEXIBLE ROLL WITH METALLIC OUTER LAYER| FR1502490|2015-11-27|FR1502490A| FR3044255B1|2015-11-27|2015-11-27|FIBER APPLICATION HEAD WITH FLEXIBLE ROLL WITH METALLIC OUTER LAYER| PCT/FR2016/000183| WO2017089659A1|2015-11-27|2016-11-17|Fibre application head with flexible roller provided with a metallic exterior layer| EP16816324.4A| EP3380309A1|2015-11-27|2016-11-17|Fibre application head with flexible roller provided with a metallic exterior layer| 相关专利
Sulfonates, polymers, resist compositions and patterning process
Washing machine
Washing machine
Device for fixture finishing and tension adjusting of membrane
Structure for Equipping Band in a Plane Cathode Ray Tube
Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
国家/地区
|